Infinite Anionic Chains Formed by Alternating Bidentately Acting [SbS4]3- Anions and [Mn(dien)]2+ Complexes in the Compound [Mn(dien)2][Mn(dien)SbS4]2
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چکیده
Dedicated to Professor Heinrich Nöth on the occasion of his 85th birthday The new compound [Mn(dien)2][Mn(dien)SbS4]2 (dien = diethylenetriamine) was synthesized under solvothermal conditions. It crystallizes in the non-centrosymmetric monoclinic space group P21 with a = 7.5736(5), b = 19.1081(16), c = 13.1174(11) Å, β = 90.022(9)◦, V = 1898.3(3) Å3, and Z = 2. The crystal structure is composed of one [Mn(dien)2] cation and an anionic chain composed of [SbS4] anions and [Mn(dien)2] cations. The [SbS4] anions connect [Mn(dien)2] ions in a μ2-fashion to form an undulated {[Mn(dien)SbS4]}2 chain running along [001]. The Mn 2+
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